Search results for "Vertical transition"

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Stabilise, balance and adjust : Framing the early years transitions of children whose parents work non‐standard hours

2022

This study examined talk by parents about the early years transitions of their children (n = 7) in the context of parental non-standard working hours and Finnish early childhood education and care (ECEC) services. Parents were interviewed at three time points: when their child was aged one, four, five or six years (a total of 21 interviews). The third interview was conducted during the COVID-19 pandemic. This article focuses on the children's ECEC transitions and the interpretative frames used by parents when talking about their work and childcare. The frames used by the parents to discuss the children's transitions were stabilising the children's lives, balancing between staying at home an…

varhaiskasvatusnon-standardworking hoursearly years transitionshorizontal transitionsCOVID-19 pandemicCOVID-19päivähoitodiskurssianalyysivanhemmatchildcare arrangementsearly childhood educationand carelife transitionslastenhoitosiirtymävaihediscourse analysisvertical transitionslapsen kehitys
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Calculation of low bandgap homopolymers: Comparison of TD-DFT methods with experimental oligomer series

2016

Made available in DSpace on 2018-12-11T17:26:45Z (GMT). No. of bitstreams: 0 Previous issue date: 2016-02-01 The performance of different DFT functionals (B3LYP, BHLYP, CAM-B3LYP, M06HF) on the prediction of vertical transition energies Evert of low bandgap homopolymers is tested against the experimentally available oligomer series (thienopyrazines and thienothiophenes). This allows for a detailed and accurate comparison on the consistency of DFT methods for chainlength evolution and polymer limit prediction, and for an understanding of geometry and time-dependent contributions to Evert by combinatorial analysis. Together with former studies on wide/medium bandgap polymers and low bandgap c…

chemistry.chemical_classificationMaterials scienceSeries (mathematics)Band gapGeneral Physics and Astronomy02 engineering and technologyPolymerVertical transition010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesOligomer0104 chemical sciencesMoment (mathematics)Combinatorial analysischemistry.chemical_compoundchemistryComputational chemistryChemical physicsPhysical and Theoretical Chemistry0210 nano-technologyChemical Physics Letters
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